{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)europium(III)
نویسندگان
چکیده
In the title complex, [CuEu(C(19)H(20)N(2)O(4))(NO(3))(3)], the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Eu(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base.
منابع مشابه
{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)erbium(III) acetone solvate
In the title complex, [CuEr(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is coordinated in a square-planar environment by two O atoms and two N atoms of a Schiff base ligand. The Er(III) ion is bis-chelated by three nitrate ligands and coordinated by four O atoms of the Schiff base ligand in a slightly distorted bicapped square-anti-prismatic environment.
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In the title complex, [CuLu(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)COCH(3), the Cu(II) ion is four-coordinated in a square-planar geometry by two O atoms and two N atoms from the deprotonated Schiff base. The Lu(III) ion is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base. A mol-ecule of acetone is present as a solvate.
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The title dinuclear complex, [EuNi(C(19)H(20)N(2)O(4))(NO(3))(3)(CH(3)OH)(2)]·2CH(3)OH, is isostructural with its Ni(II)/Pr(III) analogue. The Ni(II) ion is coordinated by two O atoms and two N atoms of a Schiff base ligand and by two methanol mol-ecules, forming a slightly distorted octa-hedral geometry. The Eu(III) ion is coordinated by six O atoms from three chelating nitrate ligands and fou...
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In the title compound, [CuZnCl(2)(C(19)H(20)N(2)O(4))], the Cu(II) ion exhibits a slightly distorted square-planar coordination geometry defined by two N atoms and two O atoms of the 6,6'-dimeth-oxy-2,2'-[propane-1,3-diylbis(nitrilo-methyl-idyne)]diphenolate Schiff base ligand. The Zn(II) ion is also four-coordinated by the two phenolate O atoms of the Schiff base ligand and by two cis-coordina...
متن کامل{μ-6,6′-Dimethoxy-2,2′-[propane-1,3-diylbis(nitrilomethylidyne)]diphenolato}trinitratocopper(II)samarium(III) acetone solvate
In the title complex, [CuSm(C(19)H(20)N(2)O(4))(NO(3))(3)]·CH(3)CO-CH(3), the Cu(II) atom is four-coordinated in a square-planar geometry by two O atoms and two N atoms of the deprotonated Schiff base. The Sm(III) atom is ten-coordinate, chelated by three nitrate groups and linked to the four O atoms of the deprotonated Schiff base.
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